Nature Communications (May 2020)

Promoting H2O2 production via 2-electron oxygen reduction by coordinating partially oxidized Pd with defect carbon

  • Qiaowan Chang,
  • Pu Zhang,
  • Amir Hassan Bagherzadeh Mostaghimi,
  • Xueru Zhao,
  • Steven R. Denny,
  • Ji Hoon Lee,
  • Hongpeng Gao,
  • Ying Zhang,
  • Huolin L. Xin,
  • Samira Siahrostami,
  • Jingguang G. Chen,
  • Zheng Chen

DOI
https://doi.org/10.1038/s41467-020-15843-3
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 9

Abstract

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Electrocatalysts which deliver high selectivity for two-electron oxygen reduction to hydrogen peroxide in acidic media are sought to replace the conventional anthraquinone process. Here, the authors develop partially oxidised palladium clusters on carbon nanotubes with near 100% selectivity.