Structural, Electrical and Optical Properties of TM (Mn and Cr) Doped BiFeO₃ Nanoparticles

Abstract

In this paper, the sol-gel technique has been employed to prepare the pure and TM (Mn, Cr) doped BiFeO3 nanoparticles. The synthesized nanoparticles were characterized using X-ray diffraction, UV-vis spectroscopy, photoluminescence, and dielectric measurements. Crystal structural analysis infers that pure and TM-doped BiFeO3 nanoparticles displayed a rhombohedral distorted perovskite structure with R3c space group, along with a minor phase of Bi2Fe4O9. Lattice parameters have been found to decrease with TM doping. The particle size, measured with the help of the XRD spectra, was found to decrease from 54.4 nm to 38.7 nm with TM doping. The bandgap, determined using the UV-vis spectra, was observed to be 1.92, 1.66, and 1.54 eV for undoped, 5% Mn, and 5% Cr-doped BiFeO3 nanoparticles, respectively. The dielectric constant shows a normal dispersion behavior at room temperature and its value increases with TM doping. The ac conductivity also increases with TM doping in BiFeO3 nanoparticles.

Keywords

• sol-gel method
• XRD
• UV-vis spectroscopy
• photoluminescence
• dielectric properties