Mechanically Mixed Thermally Expanded Graphite/Cobalt(II) Perrhenate—Co(ReO4)₂—As Electrodes in Hybrid Symmetric Supercapacitors

Abstract

A mechanically homogenized composite of expanded graphite and cobalt(II) perrhenate has been described. Cobalt(II) perrhenate was obtained in a reaction of perrhenic acid with cobalt(II) nitrate. A simple mortar homogenization method was used to enhance the intercalation of cobalt species within the carbon matrix. The specific capacitance of the composite was enhanced by 50% (to 78 F/g) in comparison to bare expanded graphite (52 F/g). The electrochemical characteristics were significantly improved, including better cyclability (7% capacitance loss), a lower resistance of the electrode material, and a lower iR drop, with respect to expanded graphite without cobalt(II) perrhenate active species. Expanded graphite, with its unique specific surface area and pore size diameter, was proved to be a potential and cheap carbon support.

Keywords

• supercapacitors
• expanded graphite
• cobalt
• perrhenate
• composite
• energy storage