Improvement of critical current density of REBa2Cu3O7-δ by increase in configurational entropy of mixing

Abstract

REBa2Cu3O7-δ (RE123, RE: rare earth) is one of the high-temperature superconductors with a transition temperature (Tc) exceeding 90 K. Because of its high-Tc and large critical current density (Jc) under magnetic fields, RE123 superconductors have been expected to play a key role in superconductivity application. To accelerate application researches on RE123-based devices, further improvements of Jc characteristics have been desired. In this study, we investigated the effects of high-entropy alloying at the RE site on the superconducting properties, through the measurements of local (intra-grain) Jc ([Formula: see text]) by a remanent magnetization method. We found that [Formula: see text] shows a trend to be improved when four or five RE elements are mixed at the RE site, which results in high configurational entropy of mixing (ΔSmix). All samples exhibited an order of few MA cm−2 which is a criterion for practical application and the highest [Formula: see text] resulted in a value of around 7.0 MA cm−2 at T = 2.0 K. Because high-entropy alloying can improve [Formula: see text] of RE123 superconductors, our entropy-engineering strategy introduced here would be useful for the development of RE123 superconducting materials available under high magnetic fields.

Keywords

• high-entropy
• material design
• cuprate superconductor