Water Science and Technology (Jan 2022)
GC/MS screening of buckthorn phytochemicals and their use to synthesize ZnO nanoparticles for photocatalytic degradation of malachite green dye in water
Abstract
Zinc oxide nanoparticles (ZnO NPs) were biosynthesized. According to gas chromatography/mass spectrometry analysis, chalcone, the main phytochemical, is probably complexed with Zn ions that are then oxidized to ZnO NPs by atmospheric O2 during heating. The ZnO NPs were characterized by thermogravimetric analysis, Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and Brunauer–Emmett–Teller surface area analysis. Sphere-like ZnO NPs were formed with 11 nm mean crystallite size, 5.2 m2 g−1 surface area, and 0.02 cm3 g−1 total pore volume. The synthesized ZnO showed excellent photocatalytic degradation (96.5±0.24% in 1 hour at 25 °C) of malachite green (MG) in aqueous solutions under ultraviolet light at optimum conditions; pH 10, MG initial concentration of 20 mg L−1, and ZnO dose of 1.5 g L−1. Also, ZnO showed very good reusability (92.9± 0.2% after five runs). The experimental data obeyed pseudo-first-order kinetics (R2 = 0.92). The photocatalysis process was dependent on the following species in the order: OH. > electron/positive hole pairs > O2.−. Moreover, photodegradation efficiency decreased in the presence of CO32−, HCO3−, and Cl−, but increased in the presence of NO3− and SO42− ions. Thus, the green synthesized ZnO NPs can be applied as an efficient photocatalyst for the removal of MG from aqueous media. HIGHLIGHTS Phytochemicals in buckthorn leaves were GC/MS screened.; Phytochemicals were applied to green synthesize mesoporous ZnO nanocatalyst.; ZnO photocatalytically degraded malachite green.; Different parameters of the photocatalytic process were studied and optimized.; Scavenging experiments were done and mechanism of photocatalysis was suggested.;
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