Molbank
(Aug 2016)
1,3-Butanediol Dibenzoate
Wataru Hakamata,
Kaho Goto,
Sakiko Ishiwata,
Rieka Ouki,
Riku Sakai,
Arisa Iizuka,
Shuta Yano,
Takako Hirano,
Toshiyuki Nishio
Affiliations
Wataru Hakamata
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Kaho Goto
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Sakiko Ishiwata
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Rieka Ouki
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Riku Sakai
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Arisa Iizuka
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Shuta Yano
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Takako Hirano
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
Toshiyuki Nishio
Department of Chemistry and Life Science, College of Bioresource Sciences, Nihon University, 1866 Kameino, Fujisawa-shi, Kanagawa 252-0880, Japan
DOI
https://doi.org/10.3390/M905
Journal volume & issue
Vol. 2016,
no. 3
p.
M905
Abstract
Read online
Environmentally friendly and straightforward methods for creating biofuels are required to promote biofuel use. Therefore, we present here a convenient and environmentally friendly direct self-aldol reaction of acetaldehyde in 100 mM borate buffer (pH 10) affording the dimer of 3-hydroxybutanal with a good yield. The product can be easily converted into 1,3-butanediol and its benzoate; therefore, our results will have a positive impact in the field of biochemical production from ethanol.
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