Green Processing and Synthesis (Dec 2022)

Value-added utilization of coal fly ash and recycled polyvinyl chloride in door or window sub-frame composites

  • Li Zhaoshuai,
  • Wang Guxia,
  • Yan Jun,
  • Qian Yongqiang,
  • Guo Shengwei,
  • Liu Yuan,
  • Li Dan

DOI
https://doi.org/10.1515/gps-2023-0002
Journal volume & issue
Vol. 12, no. 1
pp. 18727 – 40

Abstract

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Comprehensive utilization of coal fly ashes (CFA) solid waste is a worldwide urgent issue. In China, tens of millions of tons of CFA are un-utilized and stored or discarded in landfills per year, causing a significant waste of resources and a serious environmental hazard. Herein, we developed a new process to reuse CFA and recycled polyvinyl chloride (r-PVC) to produce door or window sub-frame (DWSF) composite materials, realized CFA and r-PVC trash to treasure. In this process, aluminate-modified CFA mixing with r-PVC and other additives obtain a mixture, subsequently extruding into pellets, re-extrusion, cooling, shaping, hauling, and cutting to DWSF materials. The mechanical properties of these are excellent and meet the National Standards, with static bending and tensile strengths of 33 and 13.6 MPa, respectively, and a hardness of 89.2 HRR. Compared with the traditional CaCO3-based DWSF, our CFA-based DWSFs have higher competitive both from the perspective of “carbon neutrality” and production costs. More strikingly, this process is simple, robust, and easy to industrialize, which allows large-scale, value-added utilization of CFA.

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