IUCrData (Feb 2018)

(4-Methylphenyl)methanaminium bromide hemihydrate

  • R Aarthi,
  • A Thiruvalluvar,
  • C Ramachandra Raja

DOI
https://doi.org/10.1107/S2414314618002705
Journal volume & issue
Vol. 3, no. 2
p. x180270

Abstract

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In the title hydrated salt, C8H12N+·Br−·0.5H2O, which is isostructural with its chloride congener, the water O atom lies on a crystallographic twofold axis. In the crystal, the components are linked via C—H...Br, O—H...Br, N—H...Br and N—H...O hydrogen bonds to generate (100) sheets. The sheets are linked by two weak C—H...π interactions, generating a three-dimensional network.

Keywords