Acta Crystallographica Section E (Jul 2011)

Diaquabis(5-carboxy-1H-imidazole-4-carboxylato-κ2N3,O4)iron(II)

  • Chao-Jun Du,
  • Xing-Hua Song,
  • Li-Sheng Wang,
  • Chao-Ling Du

DOI
https://doi.org/10.1107/S1600536811024779
Journal volume & issue
Vol. 67, no. 7
pp. m997 – m997

Abstract

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In the title compound, [Fe(C5H3N2O4)2(H2O)2], the FeII ion lies on an inversion centre and is coordinated by two N and two O atoms from two 5-carboxy-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral geometry. An intramolecular O—H...O hydrogen bond occurs. In the crystal, intermolecular N—H...O and O—H...O hydrogen bonds form a three-dimensional network, which consolidates the packing.