Química Nova (Jun 2014)

Glicerol como solvente verde em eficiente obtenção de beta-hidroxiésteres

  • Simone Santos de Sousa Oliveira,
  • Sorele Batista Fiaux,
  • Igor Ramon Lomba Barreto,
  • Estela Maris Freitas Muri,
  • Maria da Conceição Klaus V. Ramos,
  • Francisco Radler de Aquino Neto,
  • Luiza Rosária Sousa Dias

DOI
https://doi.org/10.5935/0100-4042.20140088
Journal volume & issue
Vol. 37, no. 3
pp. 545 – 548

Abstract

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In this work, we report a new method for obtaining racemic β-hydroxyesters by reduction of β-ketoesters. The use of glycerol as a reactional medium in selective reduction of β-ketoesters into the corresponding alcohols was shown to be a viable and more efficient alternative compared with the conventional methodology, taking into account green chemistry prerogatives.

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