Control of structural flexibility of layered-pillared metal-organic frameworks anchored at surfaces

Suttipong Wannapaiboon; Andreas Schneemann; Inke Hante; Min Tu; Konstantin Epp; Anna Lisa Semrau; Christian Sternemann; Michael Paulus; Samuel J. Baxter; Gregor Kieslich; Roland A. Fischer

doi:10.1038/s41467-018-08285-5

Nature Communications (Jan 2019)

Control of structural flexibility of layered-pillared metal-organic frameworks anchored at surfaces

Suttipong Wannapaiboon,
Andreas Schneemann,
Inke Hante,
Min Tu,
Konstantin Epp,
Anna Lisa Semrau,
Christian Sternemann,
Michael Paulus,
Samuel J. Baxter,
Gregor Kieslich,
Roland A. Fischer

Affiliations

Suttipong Wannapaiboon: Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry, Technical University of Munich
Andreas Schneemann: Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry, Technical University of Munich
Inke Hante: Chair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum
Min Tu: Chair of Inorganic Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum
Konstantin Epp: Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry, Technical University of Munich
Anna Lisa Semrau: Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry, Technical University of Munich
Christian Sternemann: Fakultät Physik/DELTA, Technische Universität Dortmund
Michael Paulus: Fakultät Physik/DELTA, Technische Universität Dortmund
Samuel J. Baxter: School of Chemistry and Biochemistry, Georgia Institute of Technology
Gregor Kieslich: Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry, Technical University of Munich
Roland A. Fischer: Chair of Inorganic and Metal-Organic Chemistry, Department of Chemistry, Technical University of Munich

DOI: https://doi.org/10.1038/s41467-018-08285-5
Journal volume & issue: Vol. 10, no. 1
pp. 1 – 10

Abstract

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Understanding the structural dynamics of flexible metal-organic frameworks at a thin-film level is key if they are to be implemented in devices. Here, Fischer and colleagues anchor flexible MOF crystallites onto substrates and identify a structural responsiveness that is distinct to that of the bulk.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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