Preparation of anthracene-based tetraperimidine hexafluorophosphate and selective recognition of chromium(III) ions

Qing-Xiang Liu; Feng Yang; Zhi-Xiang Zhao; Shao-Cong Yu; Yue Ding

doi:10.3762/bjoc.15.278

Beilstein Journal of Organic Chemistry (Nov 2019)

Preparation of anthracene-based tetraperimidine hexafluorophosphate and selective recognition of chromium(III) ions

Qing-Xiang Liu,
Feng Yang,
Zhi-Xiang Zhao,
Shao-Cong Yu,
Yue Ding

Affiliations

Qing-Xiang Liu: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China
Feng Yang: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China
Zhi-Xiang Zhao: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China
Shao-Cong Yu: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China
Yue Ding: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China

DOI: https://doi.org/10.3762/bjoc.15.278
Journal volume & issue: Vol. 15, no. 1
pp. 2847 – 2855

Abstract

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A novel anthracene-based tetraperimidine hexafluorophosphate 3 was prepared, and its structure was determined through X-ray analysis, HRMS as well as 1H and 13C NMR spectroscopy. In the cationic moiety of 3, two (N-ethylperimidinyl–C2H4)2NCH2– arms were attached to the 9- and 10-positions of anthracene. In addition, compound 3 was used as a chemosensor to research the ability to recognize Cr3+ through fluorescence and UV titrations, HRMS, as well as 1H NMR and IR spectroscopy. The results indicate that 3 is an effective chemosensor for Cr3+.

Published in Beilstein Journal of Organic Chemistry

ISSN: 1860-5397 (Online)
Publisher: Beilstein-Institut
Country of publisher: Germany
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.beilstein-journals.org/bjoc

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