Fabrication of Polyaniline Ni-Complex Catalytic Electrode by Plasma Deposition for Electrochemical Detection of Phosphate through Glucose Redox Reaction as Mediator

Abstract

We report here the preparation and characterization of polyaniline Ni-complex catalytic electrode by one-pot plasma deposition for the electrochemical detection of phosphate via the redox reaction of glucose. We first prepared a precursory solution by combining NiCl2 and 3-aminobenzoic acid in a mixed solution of methanol (MeOH) and water, and adding aniline as a conductive polymeric precursor for increasing the electron transfer potential. We then synthesized the catalytic electrode in a one-step cold plasma process by preparing the precursors on ITO glass. We characterized the obtained Ni-coordinate catalytic electrode via X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (SEM), and electrochemical methods. Electrochemical characterization produced stable redox properties of Ni3+/Ni2+ couples in a 0.1 M NaOH solution. Cyclic voltametric experiments have drastically increased electrocatalytic oxidation and reduction of glucose by increasing the concentration of phosphate (PO43−) ions using the prepared Ni-modified catalytic electrodes. From these results, the prepared catalytic electrode could be used as the electrochemical sensor for phosphate in actual water.

Keywords

• plasma deposition
• polyaniline Ni-complex catalytic electrode
• electrochemical detection
• phosphate ion
• glucose
• redox behavior of Ni³⁺/Ni²⁺ couples