Preparation and Characterization of BXFO High-Entropy Oxides

Abstract

Increasing demand for functional materials crucial for advancing new technologies has motivated significant scientific and industrial research efforts. High-entropy materials (HEMs), with tunable properties, are gaining attention for their use in high-frequency transformers, microwave devices, multiferroics, and high-density magnetic memory components. The initial exploration of HEMs started with high-entropy alloys (HASs), such as CrMnFeCoNi, CuCoNiCrAlxFe, and AlCoCrTiZn and paved the way for a multitude of HEM variations, including oxides, oxyfluorides, borides, carbides, nitrides, sulfides, and phosphides. In this study, we fabricated the high-entropy oxide (HEO) compound Bi0.5La0.1In0.1Y0.1Nd0.1Gd0.1FeO3 through the solid-state synthesis method. Magnetic measurements at 300 K show ferromagnetic behavior with significant coercivity. At the same time, this novel composition exhibits excellent dielectric properties and shows potential for electronic applications demonstrating that a high-entropy approach can expand the compositional range of rare earth multiferroics and improve the multifunctional properties in multiferroic applications.

Keywords

• multi-doping
• multiferroics
• high-entropy oxides
• bismuth ferrite
• magnetization