Crystals (May 2016)
Coordination Networks Based on Boronate and Benzoxaborolate Ligands
- Saad Sene,
- Marie Alix Pizzoccaro,
- Joris Vezzani,
- Marc Reinholdt,
- Philippe Gaveau,
- Dorothée Berthomieu,
- Sylvie Bégu,
- Christel Gervais,
- Christian Bonhomme,
- Guillaume Renaudin,
- Adel Mesbah,
- Arie van der Lee,
- Mark E. Smith,
- Danielle Laurencin
Affiliations
- Saad Sene
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Marie Alix Pizzoccaro
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Joris Vezzani
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Marc Reinholdt
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Philippe Gaveau
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Dorothée Berthomieu
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Sylvie Bégu
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- Christel Gervais
- Laboratoire de Chimie de la Matière Condensée de Paris, UMR 7574, Sorbonne Universités, UPMC Univ Paris 06, CNRS, Collège de France, Paris 75252, France
- Christian Bonhomme
- Laboratoire de Chimie de la Matière Condensée de Paris, UMR 7574, Sorbonne Universités, UPMC Univ Paris 06, CNRS, Collège de France, Paris 75252, France
- Guillaume Renaudin
- Université Clermont Auvergne, SIGMA Clermont, Institut de Chimie de Clermont-Ferrand, BP 10448, F-63000 Clermont-Ferrand, France
- Adel Mesbah
- Institut de Chimie Séparative de Marcoule, UMR 5257, CNRS CEA UM ENSCM, Bagnols-sur-Cèze 30207, France
- Arie van der Lee
- Institut Européen des Membranes, CNRS-UMR 5635, UM, Montpellier 34095, France
- Mark E. Smith
- Vice-Chancellor’s Office, University House, Lancaster University, Lancaster LA1 4YW, UK
- Danielle Laurencin
- Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM ENSCM, Montpellier 34095, France
- DOI
- https://doi.org/10.3390/cryst6050048
- Journal volume & issue
-
Vol. 6,
no. 5
p. 48
Abstract
Despite the extensive range of investigations on boronic acids (R-B(OH)2), some aspects of their reactivity still need to be explored. This is the case for the coordination chemistry of boronate anions (R-B(OH)3−), which has only recently been started to be studied. The purpose of this review is to summarize some of the key features of boronate ligands (and of their cyclic derivatives, benzoxaborolates) in materials: (i) coordination properties; (ii) spectroscopic signatures; and (iii) emerging applications.
Keywords
- boronate
- tri-hydroxyborate
- benzoxaborolate
- boronic acid
- benzoxaborole
- coordination polymer
- solid state NMR
- IR spectroscopy
- crystallography
- DFT
