Organics (Nov 2022)

Phosphonated Polyethylenimine Maghemite Nanoparticles: A Convenient Support of Palladium for Cross-Coupling Reactions

  • Clément Monteil,
  • Etienne Jean,
  • Nathalie Bar,
  • Didier Villemin

DOI
https://doi.org/10.3390/org3040032
Journal volume & issue
Vol. 3, no. 4
pp. 491 – 501

Abstract

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Phosphonated polyethylenimine grafted on iron oxide nanoparticles was used as a magnetic support for loading palladium. This cheap and accessible heterogeneous catalyst demonstrated good efficiency in Suzuki-Miyaura, Mizoroki-Heck, and Tsuji-Trost couplings. The nanocomposite is resistant to harsh conditions and can therefore be recycled up to 10 cycles with high catalyst efficiency.

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