The Effect of Slag on the Mechanical Properties of Coralline-Activated Materials and the Formation and Transformation of Mineral Crystals

Abstract

In this study, coralline-activated materials were prepared using ball-milled coral powder as cementitious material and coral sand as fine aggregate. XRF (X-ray fluorescence) and chemical dissolution tests were carried out to determine the content and reactivity of various elements in coral powder. The compressive strength of the developed composites was evaluated at different ages, and the formation and transformation of mineral crystals in coralline-activated samples were further analyzed by XRD (X-ray diffractometer). The results show that the calcium content in coral powder was as high as 89.5% (loss on ignition). However, only 56% of the active calcium could participate in the polymerization reaction. The silicon and aluminum content was too low, and the slag addition could improve the deficiency of silicon and aluminum in coral powder. With the increase in slag content (from 0% to 50%), the compressive strength of the composites increases significantly. Nevertheless, the enhancement is not pronounced when the slag content exceeds 50%. The increase in slag amount can stimulate the transformation of calcium minerals, e.g., aragonite and calcite, into hydrated calcium silicate and calcium aluminosilicate gels, which significantly enhances the resulting compressive strength.

Keywords

• alkali-activated materials
• coral powder
• active calcium and silicon
• crystal
• compressive strength