Acta Crystallographica Section E (Aug 2008)

Bis(O,O′-diphenethyl dithiophosphato-κ2S,S′)bis(4-methylpyridine-κN)nickel(II)

  • Jian-Shen Feng,
  • Yu Cheng,
  • Li-Ke Zou,
  • Bin Xie,
  • Xiu-Lan Zhang

DOI
https://doi.org/10.1107/S1600536808020898
Journal volume & issue
Vol. 64, no. 8
pp. m1022 – m1022

Abstract

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The title complex, [Ni(C16H18O2PS2)2(C6H7N)2], exhibits a roughly octahedral coordination geometry. The NiII atom lies on an inversion centre and is coordinated by four S atoms of O,O′-diphenethyl dithiophosphate molecules and two N atoms of 4-methylpyridine molecules. Important geometric data include Ni—N = 2.100 (3) Å, and Ni—S = 2.5101 (10) and 2.4772 (11) Å.