Crystals (Oct 2023)

Growth of Germanium Thin Films on Sapphire Using Molecular Beam Epitaxy

  • Emmanuel Wangila,
  • Peter Lytvyn,
  • Hryhorii Stanchu,
  • Calbi Gunder,
  • Fernando Maia de Oliveira,
  • Samir Saha,
  • Subhashis Das,
  • Nirosh Eldose,
  • Chen Li,
  • Mohammad Zamani-Alavijeh,
  • Mourad Benamara,
  • Yuriy I. Mazur,
  • Shui-Qing Yu,
  • Gregory J. Salamo

DOI
https://doi.org/10.3390/cryst13111557
Journal volume & issue
Vol. 13, no. 11
p. 1557

Abstract

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Germanium films were grown on c-plane sapphire with a 10 nm AlAs buffer layer using molecular beam epitaxy. The effects of Ge film thickness on the surface morphology and crystal structure were investigated using ex situ characterization techniques. The nucleation of Ge proceeds by forming (111) oriented three-dimensional islands with two rotational twin domains about the growth axis. The boundaries between the twin grains are the origin of the 0.2% strain and tilt grains. The transition to a single-grain orientation reduces the strain and results in a better-quality Ge buffer. Understanding the role of thickness on material quality during the Ge(111)/Al2O3(0001) epitaxy is vital for achieving device quality when using group IV material on the sapphire platform.

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