Amine-Modified Biochar for the Efficient Adsorption of Carbon Dioxide in Flue Gas

Abstract

Biochar-based carbonaceous adsorbents are gaining interest due to their high availability, ease of modification, and low cost; however, they show limited adsorption of CO2 in flue gas due to common textural properties. In this study, TEPA-modified biochar was used to prepare a solid amine adsorbent for the efficient capture of CO2 in flue gas. First, the porous biochar was prepared with FeCl3, Mg(NO3)2, and H2O (g) as activators and walnut shells as carbon sources. Next, the biochar was modified with TEPA to obtain a solid amine adsorbent. Porous texture properties and sample surface functional groups were characterized, and we measured the adsorption CO2 of the amine-modified biochar in a breakthrough adsorption device. Results showed that biochar has a large specific surface area (744.38 m2 g−1), a total pore volume of 1.41 cm3 g−1, and a high mesoporous volume ratio (82.7%). The high pore volume provided a more efficient support space for loading tetraethylenepentamine (TEPA). The adsorbent had an excellent CO2 adsorption capacity, corresponding to 2.82 mmol g−1, which increased to 3.31 mmol g−1 and kept water resistance at 10% H2O (g) simulated flue gas (SFG). The FTIR analysis showed that H2O (g) inhibited urea production after cyclic adsorption. Therefore, solid amine adsorbent created by amine-modified biochar has potential advantages in its application for capturing CO2 in SFG.

Keywords

• walnut shell
• biochar
• coactivation
• adsorbent
• CO₂ adsorption