Biogenic mediated green synthesis of NiO nanoparticles for adsorptive removal of lead from aqueous solution

Abstract

The spread of heavy metal in water bodies, particularly lead (Pb), has occurred as a global threat to human existence. In this study, NiO nanoparticles (NPs) was prepared by coprecipitation approach using Hagenia abyssinica plant extract mediated as a reducing and template agent for the removal of Pb from aqueous solution. X-ray crystallographic diffraction (XRD), Scanning electron microscopy (SEM), Fourier transform infrared (FTIR), and Brunauer-Emmett-Teller (BET) techniques were employed for the characterization of as prepared NiO NPs. The efficacy of adsorbent was evaluated on the removal of Pb2+ by varying the adsorptive parameters such as pH, Bio-NiO amount, interaction time, and Pb2+ concentration. The adsorption was 99.99% at pH, 0.06 g of NiO NPs dose, 60 mg L−1 concentrations of Pb2+ within 80 min contact time. The higher removal efficiency is could be due to higher surface area (151 m2g-1). The adsorption process was best fitted with Freundlich isotherm and pseudo-second order kinetic models, implying that it was chemical adsorption on the heterogeneous surface. The adsorption intensity (n) was found to be 1/n < 1 (0.47) indicating adsorption of Pb2+ on the surface of Bio-NiO NPs was favorable with a maximum adsorption capacity 60.13 mg g−1. The reusability studies confirmed that the synthesized bio-NiO NPs were an effective adsorbent for removing Pb2+ from aqueous solution up to five cycles.

Keywords

• Adsorption
• NiO NPs
• Hagenia abyssinica
• Heavy metals
• Green synthesis