Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов (Dec 2012)
PHOTOCHEMICAL SYNTHESIS OF URANIUM OXIDE NANOCLUSTERS AND THEIR DEPOSITION ON THE SURFACE OF OXIDIZED ALUMINUM
Abstract
The processes of the photochemical formation of nanoclusters of the tetra- and pentavalent uranium complexes with organic ligands on light-diode irradiation (430 - 450 nm) of UO2(ClO4)3*5H2O solutions in acetone were studied by the methods of electronic and IR absorption. The possibility for deposition of the complexes of tetra- and pentavalent uranium from the photocondensation products of acetone on the porous surface of oxidized aluminum was established.