Elemental distribution and source analysis of atmospheric aerosols from Meycauayan, Bulacan, Philippines
Jumar Cadondon,
Edgar Vallar,
Floro Junior Roque,
Ofelia Rempillo,
Paulito Mandia,
Aileen Orbecido,
Arnel Beltran,
Custer Deocaris,
Vernon Morris,
Lawrence Belo,
Maria Cecilia Galvez
Affiliations
Jumar Cadondon
Environment And RemoTe sensing researcH (EARTH) Laboratory, Department of Physics, College of Science, De La Salle University, Manila 0922, Philippines; Division of Physical Sciences and Mathematics, College of Arts and Sciences, University of the Philippines Visayas, Miagao 5023, Philippines; Corresponding author. Division of Physical Sciences and Mathematics, College of Arts and Sciences, University of the Philippines Visayas, Miagao 5023, Philippines.
Edgar Vallar
Environment And RemoTe sensing researcH (EARTH) Laboratory, Department of Physics, College of Science, De La Salle University, Manila 0922, Philippines
Floro Junior Roque
Environment And RemoTe sensing researcH (EARTH) Laboratory, Department of Physics, College of Science, De La Salle University, Manila 0922, Philippines
Ofelia Rempillo
Environment And RemoTe sensing researcH (EARTH) Laboratory, Department of Physics, College of Science, De La Salle University, Manila 0922, Philippines
Paulito Mandia
Environment And RemoTe sensing researcH (EARTH) Laboratory, Department of Physics, College of Science, De La Salle University, Manila 0922, Philippines
Aileen Orbecido
Department of Chemical Engineering, Gokongwei College of Engineering, De La Salle University, Manila 0922, Philippines
Arnel Beltran
Department of Chemical Engineering, Gokongwei College of Engineering, De La Salle University, Manila 0922, Philippines
Custer Deocaris
Philippine Nuclear Research Institute, Department of Science and Technology, Quezon City, Philippines
Vernon Morris
School of Mathematical and Natural Sciences, New College for Interdisciplinary Arts and Sciences, Arizona State University PO Box 37100, MC 1251, Phoenix, AZ, USA
Lawrence Belo
Department of Chemical Engineering, Gokongwei College of Engineering, De La Salle University, Manila 0922, Philippines
Maria Cecilia Galvez
Environment And RemoTe sensing researcH (EARTH) Laboratory, Department of Physics, College of Science, De La Salle University, Manila 0922, Philippines
One of the industrialized cities in the Philippines is Meycauayan, Bulacan. This study reports the elemental distribution and source apportionment in eight varying land cover-land use type sampling points located along the Marilao-Meycauayan- Obando Rivers System. Elemental analysis was conducted using a scanning electron microscope coupled with energy dispersive x-ray. Cu, Pb, Zn, Cr, Mn, As, Cd, Co, Fe, Ni, Ti, and V concentrations were determined using Inductively Coupled Plasma Mass Spectrometry, and Hg concentrations by Mercury analyzer. Principal component analysis (PCA), hierarchical cluster analysis (HCA), and Pearson's r correlation were used to analyze different sources of heavy metals and its corresponding land use-land cover type. The aerosol samples showed the presence of heavy metals Pb and Hg, elements that were also detected in trace amounts in the water measurements. Concentrations of heavy metals such as Cu, Fe, Pb, Zn, V, Ni, and As found in the atmospheric aerosols and urban dusts were attributed to anthropogenic sources such as residential, commercial and industrial wastes. Other source of aerosols in the area were traffic and crustal emissions in Meycauayan. Using HCA, there are 3 clusters observed based on the similar sets of heavy metals: (1) AQS1 (Caingin), AQS2 (Banga), and AQS8 (Malhacan); (2) AQS3(Calvario), AQS4 (Camalig), and AQS5(Langka); (3) AQS1(Sto Nino-Perez), and (AQS7) (Sterling). These groups are related based on different land use setting such as residential/commercial, agricultural, and commercial/industrial areas. Our study recommends the need to address heavy metal pollution in Meycauayan in support to the ongoing implementation of laws and regulations by the local and private sectors.
