Nature Communications (Jul 2019)

Stabilizing polymer electrolytes in high-voltage lithium batteries

  • Snehashis Choudhury,
  • Zhengyuan Tu,
  • A. Nijamudheen,
  • Michael J. Zachman,
  • Sanjuna Stalin,
  • Yue Deng,
  • Qing Zhao,
  • Duylinh Vu,
  • Lena F. Kourkoutis,
  • Jose L. Mendoza-Cortes,
  • Lynden A. Archer

DOI
https://doi.org/10.1038/s41467-019-11015-0
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 11

Abstract

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Here the authors use cationic chain transfer agents to prevent degradation of ether electrolytes by arresting uncontrolled polymer growth at the anode. This work provides a fundamental strategy for extending the high voltage stability of these electrolytes to potentials above conventionally accepted limits.