Acta Crystallographica Section E (Oct 2009)

Tetraaquabis(6-carboxy-1H-benzimidazole-5-carboxylato-κN3)nickel(II) dimethylformamide disolvate dihydrate

  • Hao Wang,
  • Wen-Dong Song,
  • Shi-Jie Li,
  • Pei-Wen Qin,
  • Shi-Wei Hu

DOI
https://doi.org/10.1107/S1600536809038069
Journal volume & issue
Vol. 65, no. 10
pp. m1258 – m1258

Abstract

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The title compound, [Ni(C9H45N2O4)2(H2O)4]·2C3H7NO·2H2O, has the NiII center coordinated by four water molecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxylate ligands in an octahedral geometry. The molecule interacts with the solvent water and dimethylformamide molecules through N—H...O and O—H...O hydrogen bonds to form a three-dimensional supramolecular network. The metal atom lies on a center of inversion.