5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane

K. Gayathri; S. Sathya; G. Usha; G. Ramanjaneya Reddy; S. Balasubramanian

doi:10.1107/S1600536813031164

Acta Crystallographica Section E (Jan 2014)

5,5,7,12,12,14-Hexamethyl-1,8-bis(4-nitrobenzyl)-1,4,8,11-tetraazacyclotetradecane

K. Gayathri,
S. Sathya,
G. Usha,
G. Ramanjaneya Reddy,
S. Balasubramanian

Affiliations

K. Gayathri: PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India
S. Sathya: PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India
G. Usha: PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India
G. Ramanjaneya Reddy: Department of Inorganic Chemistry, University of Madras, Maraimalai Campus, Chennai-25, Tamilnadu, India
S. Balasubramanian: Department of Inorganic Chemistry, University of Madras, Maraimalai Campus, Chennai-25, Tamilnadu, India

DOI: https://doi.org/10.1107/S1600536813031164
Journal volume & issue: Vol. 70, no. 1
pp. o50 – o50

Abstract

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The asymmetric unit of the title compound, C30H46N6O4, contains one half-molecule. The C(benzene)—C(CH2)—N—C(—Me) torsion angle is −79.89 (13)° suggesting a synclinal orientation of the nitrobenzene ring with respect to the macrocycle. The conformation of the macrocycle is stabilized by intramolecular N—H...N hydrogen bonds.

Published in Acta Crystallographica Section E

ISSN: 1600-5368 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://journals.iucr.org/e/

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