Influence of the Mesoporous Polymer Matrix Nature on the Formation of Catalytically Active Ruthenium Nanoparticles

Mikhail Sulman; Valentin Doluda; Maksim Grigoryev; Oleg Manaenkov; Anastasiya Filatova; Vladimir Molchanov; Alexander Sidorov; Alexey Bykov; Irin Shkileva; Aleksandrina Sulman; Barry Stein; Valentina Matveeva

doi:10.9767/bcrec.10.3.8824.313-323

Bulletin of Chemical Reaction Engineering & Catalysis (Dec 2015)

Influence of the Mesoporous Polymer Matrix Nature on the Formation of Catalytically Active Ruthenium Nanoparticles

Mikhail Sulman,
Valentin Doluda,
Maksim Grigoryev,
Oleg Manaenkov,
Anastasiya Filatova,
Vladimir Molchanov,
Alexander Sidorov,
Alexey Bykov,
Irin Shkileva,
Aleksandrina Sulman,
Barry Stein,
Valentina Matveeva

Affiliations

Mikhail Sulman: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Valentin Doluda: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Maksim Grigoryev: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Oleg Manaenkov: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Anastasiya Filatova: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Vladimir Molchanov: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Alexander Sidorov: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Alexey Bykov: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Irin Shkileva: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Aleksandrina Sulman: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation
Barry Stein: Department of Biology, Indiana University, Bloomington, IN 47405, United States
Valentina Matveeva: Department of Biotechnology and Chemistry, Tver State Technical University, A. Nikitina str., 22, Tver 170026, Russian Federation

DOI: https://doi.org/10.9767/bcrec.10.3.8824.313-323
Journal volume & issue: Vol. 10, no. 3
pp. 313 – 323

Abstract

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This paper reports on ruthenium nanoparticles formation and stabilization by hypercrosslinked poly-styrene and the catalytic properties of the nanocomposites obtained. Hypercrosslinked polystyrene with functional groups and without them was used. The nanocomposites were characterized using low-temperature nitrogen physisorption, X-ray photoelectron spectroscopy and transmission electron mi-croscopy. It is established that the tertiary amine group of the support influences both formation of ru-thenium nanoparticles, and their catalytic properties in the selective hydrogenation of D-glucose. Copyright © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Published in Bulletin of Chemical Reaction Engineering & Catalysis

ISSN: 1978-2993 (Online)
Publisher: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Country of publisher: Indonesia
LCC subjects: Technology: Chemical technology: Chemical engineering
Website: https://journal.bcrec.id/index.php/bcrec

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