Multiyne chains chelating osmium via three metal-carbon σ bonds

Qingde Zhuo; Jianfeng Lin; Yuhui Hua; Xiaoxi Zhou; Yifan Shao; Shiyan Chen; Zhixin Chen; Jun Zhu; Hong Zhang; Haiping Xia

doi:10.1038/s41467-017-02120-z

Nature Communications (Dec 2017)

Multiyne chains chelating osmium via three metal-carbon σ bonds

Qingde Zhuo,
Jianfeng Lin,
Yuhui Hua,
Xiaoxi Zhou,
Yifan Shao,
Shiyan Chen,
Zhixin Chen,
Jun Zhu,
Hong Zhang,
Haiping Xia

Affiliations

Qingde Zhuo: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Jianfeng Lin: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Yuhui Hua: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Xiaoxi Zhou: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Yifan Shao: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Shiyan Chen: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Zhixin Chen: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Jun Zhu: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Hong Zhang: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University
Haiping Xia: State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University

DOI: https://doi.org/10.1038/s41467-017-02120-z
Journal volume & issue: Vol. 8, no. 1
pp. 1 – 7

Abstract

Read online

Metal-carbon σ bonds mark the basis of organometallic chemistry, but the formation of multiple such bonds between single organic and metal entities remains a challenge. Here, the authors report a one-pot aromaticity-driven method to construct osmium-based multidentate complexes containing three metal-carbon σ bonds from multiyn chains.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

About the journal