Acta Crystallographica Section E (Aug 2009)

Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate

  • Vahid Amani,
  • Zeinab Khoshtarkib,
  • Khadijeh Kalateh,
  • Robabeh Alizadeh,
  • Roya Ahmadi

DOI
https://doi.org/10.1107/S1600536809024180
Journal volume & issue
Vol. 65, no. 8
pp. m848 – m849

Abstract

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The asymmetric unit of the title compound, [HgCl2(C26H20N2)]·0.5CH3CN, contains two crystallographically independent [HgCl2(C26H20N2)] molecules and one acetonitrile solvent molecule. The HgII atoms are four-coordinated in distorted tetrahedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61 (3) and 66.00 (3)° in the two molecules. In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distances = 3.809 (1), 3.686 (1), 3.986 (1), 3.877 (1), 3.697 (1), 3.789 (1), 3.745 (1), 3.797 (1) and 3.638 (1) Å] may stabilize the structure.