Corrigendum

Abstract

Zarovnaya, I. S., Sadkova, I. V., Kulakov, I. V., Dulnev, P. G., Palchikov, V. A. (2013). New oxazіlines with sulfolane frame. Bull. Dnipropetrovsk Univ. Ser. Chem., 21(20), 21–30 (in Russian). doi: https://doi.org/10.15421/081315 Zarovnaya, I. S., Tokar, A. V., Palchikov, V. A. (2014). Features of interaction isomeric 4-amino-tetrahydrothiophen-3-ol-1,1-dioxide with some C-electrophilic reagents. Bull. Dnipropetrovsk Univ. Ser. Chem., 22(2), 39–46 (in Ukrainian). doi: https://doi.org/10.15421/081419 Aminolysis of 3,4-epoxysulfolane in aqueous media leads to a very complex mixture of products with unresolved stereochemistry. Herein, we report revised data refer to our previously published results in this journal. According to our 2D NMR and XRD study sulfolane-based amino alcohols with m.p. 189–192˚С and 102–105˚С have cis- and trans-configuration respectively (CCDC 1527144 for cis-isomer, CCDC 1527143 for trans-isomer). Detailed analytical data obtained in the course of our work will be useful for the stereochemical identification of new sulfolane derivatives.

Keywords

• aminolysis, 3,4-epoxysulfolane, configuration, amino alcohol