Chemical and Mineralogical Characterization of Recycled Aggregates from Construction and Demolition Waste from Mexico City

Abstract

In this study, four samples of recycled aggregates from the construction and demolition waste of Mexico City were characterized in order to find innovative uses for these types of materials. Gravel and sand from a recycling plant were analyzed, as well as aggregates produced in the laboratory from demolished concrete collected from landfills. The characterization was carried out by means of XRD (X-ray Diffraction), chemical microanalysis (EDS), X-ray fluorescence (XRF), pH measurement, and sieve analysis. The minerals present in the analyzed materials were feldspars, cristobalite and pyroxene, which corresponded to the natural aggregates, as well as variable amounts of calcite, a product of the carbonation of the cement paste adhered to these aggregates, and in a smaller proportion, calcium hemicarboaluminate, rosenhanite, and tobermorite. The quality (amount of cement) of the original concrete has a great influence on the granulometry and the chemical–mineralogical composition of the aggregates, since there will be different quantities and qualities of the cement paste adhered to the aggregates depending on their size. Finally, the pH values measured in all samples fluctuated between 10.15 and 12.08, suggesting that these materials can be used in soil stabilization or in agricultural applications.

Keywords

• recycled aggregates
• cement paste
• carbonation
• calcite
• pH