Rejuvenating LiNi0.5Co0.2Mn0.3O2 cathode directly from battery scraps
Yaqing Guo,
Chi Guo,
Pengjie Huang,
Qigao Han,
Fuhe Wang,
Hao Zhang,
Honghao Liu,
Yuan-Cheng Cao,
Yonggang Yao,
Yunhui Huang
Affiliations
Yaqing Guo
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 China; State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Chi Guo
Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Optoelectronic Materials & Technology, Jianghan University, Wuhan 430056, China
Pengjie Huang
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Qigao Han
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Fuhe Wang
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Hao Zhang
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 China
Honghao Liu
Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Optoelectronic Materials & Technology, Jianghan University, Wuhan 430056, China
Yuan-Cheng Cao
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China; Corresponding authors.
Yonggang Yao
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 China; Corresponding authors.
Yunhui Huang
State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 China; Corresponding authors.
Battery recycling is indispensable for alleviating critical material shortages and enabling sustainable battery applications. However, current methods mostly focus on spent batteries, which not only require sophisticated disassembly and material extraction but also have unknown chemistries and states of health, resulting in high costs and extreme challenges to achieve regeneration. Here, we propose the direct recycling and effective regeneration of air-degraded LiNi0.5Co0.2Mn0.3O2 (NCM523) cathode directly from battery scraps generated during battery manufacturing. The NCM523 shows surface degradation only a few nanometers deep and accordingly can be regenerated without adding Li, achieving restored properties (170 mAh g−1 at 0.1 C, 92.7% retention after 1000 cycles) similar to those of fresh commercial materials. EverBatt analysis shows that scrap recycling has a profit of $1.984 kg−1, which is ∼10 times higher than conventional recycling, making it practical and economical to rejuvenate slightly degraded electrode materials for sustainable battery manufacturing.
