Nature Communications (Mar 2023)

Screw sense excess and reversals of helical polymers in solution

  • Francisco Rey-Tarrío,
  • Rafael Rodríguez,
  • Emilio Quiñoá,
  • Félix Freire

DOI
https://doi.org/10.1038/s41467-023-37405-z
Journal volume & issue
Vol. 14, no. 1
pp. 1 – 9

Abstract

Read online

Reversals are structural motifs found in helical polymers that are difficult to determine experimentally. Here, the authors turn to photochemical electrocyclization as a tool to establish their presence and estimate excess screw sense in solution.