Química Nova (Jan 2012)

Identificação de extratos etanólicos de madeiras utilizando seu espectro eletrônico de absorção e análise multivariada

  • Alexandre Ataide da Silva,
  • Eduardo Sanches Pereira do Nascimento,
  • Daniel Rodrigues Cardoso,
  • Douglas Wagner Franco

DOI
https://doi.org/10.1590/S0100-40422012000300023
Journal volume & issue
Vol. 35, no. 3
pp. 563 – 566

Abstract

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The application of multivariate analysis to spectrophotometric (UV) data was explored for distinguishing extracts of cachaça woods commonly used in the manufacture of casks for aging cachaças (oak, cabreúva-parda, jatobá, amendoim and canela-sassafrás). Absorbances close to 280 nm were more strongly correlated with oak and jatobá woods, whereas absorbances near 230 nm were more correlated with canela-sassafrás and cabreúva-parda. A comparison between the spectrophotometric model and the model based on chromatographic (HPLC-DAD) data was carried out. The spectrophotometric model better explained the variance data (PC1 + PC2 = 91%) exhibiting potential as a routine method for checking aged spirits.

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