Near‐Infrared Emission Perovskites for Multifunctional Bioimaging
Tianchi Wang,
Jiabo Sun,
Zhaowei Teng,
Shuyi Yao,
Junheng Yuan,
Lulu Han,
Dedan Mu,
Hao Song,
Xue Yu,
Xuhui Xu
Affiliations
Tianchi Wang
The Central Laboratory and Department of Orthopedic The Second Affiliated Hospital of Kunming Medical University Kunming Yunnan 650106 P. R. China
Jiabo Sun
Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming Yunnan 650093 P. R. China
Zhaowei Teng
The Central Laboratory and Department of Orthopedic The Second Affiliated Hospital of Kunming Medical University Kunming Yunnan 650106 P. R. China
Shuyi Yao
Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming Yunnan 650093 P. R. China
Junheng Yuan
Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming Yunnan 650093 P. R. China
Lulu Han
Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming Yunnan 650093 P. R. China
Dedan Mu
Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming Yunnan 650093 P. R. China
Hao Song
Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming Yunnan 650093 P. R. China
Xue Yu
School of Mechanical Engineering Chengdu University Chengdu Sichuan 610106 P. R. China
Xuhui Xu
The Central Laboratory and Department of Orthopedic The Second Affiliated Hospital of Kunming Medical University Kunming Yunnan 650106 P. R. China
Bioimaging with remarkable noninvasive nature, ultrahigh resolution and sensitivity allows detection of pathologies of bones, organs, and tissues. Nevertheless, the achievement of more complete information in vivo is challenged by the necessity of multiple photodetectors with diverse response ranges. Herein, a multifunctional bioimaging with Cs2AgInCl6:Yb3+ perovskites via a single InGaAs detector for superior tissue presentation is realized in this work. Co‐incorporation of foreign dopant contributes to alterations of local structural symmetry of the Cs2AgInCl6 host, disruption of parity‐forbidden transitions, and reduction in electron–phonon coupling strength, thereby boosting the near‐infrared (NIR) intensity by 40‐fold of the corresponding perovskites drastically. Moreover, an X‐ray excited NIR light output is 2.83 times that of commercial Bi4Ge3O12 scintillators. Thanks to the efficient NIR emission, the versatile perovskites film endows a multifunctional bioimaging with detailed information of biological tissue in vivo, which fundamentally offers viable avenues for promoting bioimaging technology with integrated access of tissue presentation.
