Acta Crystallographica Section E: Crystallographic Communications (Jun 2015)

Crystal structure of poly[[μ-4-(hydroxymethyl)pyridine-κ2N:O][4-(hydroxymethyl)pyridine-κN](μ-thiocyanato-κ2N:S)(thiocyanato-κN)cadmium]

  • Julia Werner,
  • Inke Jess,
  • Christian Näther

DOI
https://doi.org/10.1107/s2056989015008890
Journal volume & issue
Vol. 71, no. 6
pp. m129 – m130

Abstract

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The crystal structure of the title compound, [Cd(NCS)2(C6H7NO)2]n is made up of Cd2+ cations that are coordinated by three thiocyanate ligands and three 4-(hydroxymethyl)pyridine ligands within distorted N4OS octahedra. The asymmetric unit consists of one Cd2+ cation, two thiocyanate anions and two 4-(hydroxymethyl)pyridine ligands in general positions. Two Cd2+ cations are linked by two μ-1,3 N- and S-bonding thioycanate anions into dimers which are further linked into branched chains along [100] by two μ-1,6 N- and O-bonding 4-(hydroxymethyl)pyridine ligands. One additional N-bonded 4-(hydroxymethyl)pyridine ligand and one additional N-bonded thiocyanate anion are only terminally bonded to the metal cation. Interchain O—H...S hydrogen bonds between the hydroxy H atoms and one of the thiocyanate S atoms connect the chains into a three-dimensional network.

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