Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Alexander S. Zaguzin; Taisiya S. Sukhikh; Ilyas F. Sakhapov; Vladimir P. Fedin; Maxim N. Sokolov; Sergey A. Adonin

doi:10.3390/molecules27041305

Molecules (Feb 2022)

Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Alexander S. Zaguzin,
Taisiya S. Sukhikh,
Ilyas F. Sakhapov,
Vladimir P. Fedin,
Maxim N. Sokolov,
Sergey A. Adonin

Affiliations

Alexander S. Zaguzin: South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia
Taisiya S. Sukhikh: Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia
Ilyas F. Sakhapov: South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia
Vladimir P. Fedin: Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia
Maxim N. Sokolov: Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia
Sergey A. Adonin: South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia

DOI: https://doi.org/10.3390/molecules27041305
Journal volume & issue: Vol. 27, no. 4
p. 1305

Abstract

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Metal-organic frameworks [M2(2-I-bdc)2bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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