Acta Crystallographica Section E (May 2010)

Bis(1,10-phenanthroline-κ2N,N′)(sulfato-κ2O,O′)zinc(II) propane-1,3-diol solvate

  • Jiang-Dong Cui,
  • Kai-Long Zhong,
  • Yan-Yun Liu

DOI
https://doi.org/10.1107/S1600536810014194
Journal volume & issue
Vol. 66, no. 5
pp. m564 – m564

Abstract

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In the title compound, [Zn(SO4)(C12H8N2)2]·C3H8O2, the Zn2+ ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O′-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO2N4 octahedral geometry for the metal ion. The complete propane-1,3-diol molecule is generated by crystallographic twofold symmetry and two O—H...O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group.