Acta Crystallographica Section E (Jun 2011)

Aqua(pyridine-3-carboxylic acid-κN)(pyridine-2,6-dicarboxylato-κ3O2,N,O6)copper(II) monohydrate

  • Ting Ting Chen,
  • Yan Fang Shang,
  • Xia Xi,
  • Yue Hua Zhang,
  • Nan Ping Wang

DOI
https://doi.org/10.1107/S160053681101926X
Journal volume & issue
Vol. 67, no. 6
pp. m809 – m809

Abstract

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In the title CuII complex, [Cu(C7H3NO4)(C6H5NO2)(H2O)]·H2O, the environment of the Cu2+ ion is a distorted square pyramid with the axial site occupied by the O atom from the coordinated water molecule and the square base formed by two O and two N atoms from the tridentate anion and the neutral monodentate pyridine-3-carboxylic acid ligand. O—H...O hydrogen bonds, as well as π–π interactions [centroid–centroid distance = 3.945 (3) Å] contribute to the stabilization of this structure.