Nature Communications (Jan 2019)
Direct access to poly(glycidyl azide) and its copolymers through anionic (co-)polymerization of glycidyl azide
Abstract
Poly(glycidyl azide) is an excellent energetic binder or plasticizer, however its production relies on post-modificaiton strategies. Here, the authors directly produced Poly(glycidyl azide) via anionic ring-opening polymerization of glycidyl azide monomer, which is additionally co-polymerized with CO2 and epoxides.