Nature Communications (Jan 2019)

Direct access to poly(glycidyl azide) and its copolymers through anionic (co-)polymerization of glycidyl azide

  • Senthil K. Boopathi,
  • Nikos Hadjichristidis,
  • Yves Gnanou,
  • Xiaoshuang Feng

DOI
https://doi.org/10.1038/s41467-018-08251-1
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 9

Abstract

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Poly(glycidyl azide) is an excellent energetic binder or plasticizer, however its production relies on post-modificaiton strategies. Here, the authors directly produced Poly(glycidyl azide) via anionic ring-opening polymerization of glycidyl azide monomer, which is additionally co-polymerized with CO2 and epoxides.