Facile Synthesis of Sea-Urchin-like VN as High-Performance Anode for Lithium-Ion Batteries
Zhaowei Hu,
Weifeng Huang,
Huifang Li,
Yizhou Zhang,
Peng Wang,
Xiaojun Wang,
Zhiming Liu
Affiliations
Zhaowei Hu
Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials, College of Electromechanical Engineering, Qingdao University of Science & Technology, Qingdao 266061, China
Weifeng Huang
School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China
Huifang Li
Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials, College of Electromechanical Engineering, Qingdao University of Science & Technology, Qingdao 266061, China
Yizhou Zhang
Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials, College of Electromechanical Engineering, Qingdao University of Science & Technology, Qingdao 266061, China
Peng Wang
Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials, College of Electromechanical Engineering, Qingdao University of Science & Technology, Qingdao 266061, China
Xiaojun Wang
Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials, College of Electromechanical Engineering, Qingdao University of Science & Technology, Qingdao 266061, China
Zhiming Liu
Shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials, College of Electromechanical Engineering, Qingdao University of Science & Technology, Qingdao 266061, China
Lithium-ion batteries are still the main theme of the contemporary market. Commercial graphite has struggled to meet the demand of high energy density for various electronic products due to its low theoretical capacity. Therefore, exploring for a new anode with high capacity is important. Vanadium nitride has attracted widespread attention due to its high theoretical specific capacity and good chemical/thermal stability. However, vanadium nitride is accompanied by huge volume expansion and nanoparticle agglomeration during the electrochemical reaction, which limits its application. Herein, sea-urchin-like vanadium nitride (SUK-VN) was successfully prepared with a simple hydrothermal method combined with an annealing strategy to boost the actual capacity of the vanadium nitride. The special sea-urchin-like morphology effectively suppresses the agglomeration of vanadium nitride nanoparticles and exposes more reactive sites, which facilitates the electrochemical performance of electrode materials. In the half-cells, sea-urchin-like vanadium nitride exhibits a specific capacity of 361.5 mAh g−1 at 0.1 A g−1 after 60 cycles, and even still achieves a specific capacity of 164.5 with a Coulomb efficiency of approximately 99.9% at 1 A g−1 after 500 cycles. Such a strategy provides the potential to enhance the electrochemical properties of vanadium nitride anodes in terms of solving the nanoparticle agglomeration.
