EPJ Web of Conferences (Mar 2013)

Exploring Higher-Lying Electronic States of a Molecular Switch by Coherent Triggered-Exchange 2D Electronic Spectroscopy

  • Nuernberger P.,
  • Buback J.,
  • Kullmann M.,
  • Ruetzel S.,
  • Brixner T.

DOI
https://doi.org/10.1051/epjconf/20134105001
Journal volume & issue
Vol. 41
p. 05001

Abstract

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We use pump-repump-probe transient absorption spectroscopy to investigate the role of higher-lying electronic states in the photochemistry of a molecular switch. Moreover, replacing the pump pulse by a pulse-shaper-generated phase-stable double pulse, triggered-exchange two-dimensional (TE2D) electronic spectroscopy is established in the visible regime.