Phosphorus-Doped Graphene Electrocatalysts for Oxygen Reduction Reaction
Xinxing Zhan,
Xin Tong,
Manqi Gu,
Juan Tian,
Zijian Gao,
Liying Ma,
Yadian Xie,
Zhangsen Chen,
Hariprasad Ranganathan,
Gaixia Zhang,
Shuhui Sun
Affiliations
Xinxing Zhan
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
Xin Tong
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
Manqi Gu
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
Juan Tian
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
Zijian Gao
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
Liying Ma
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
Yadian Xie
Key Laboratory of Low-Dimensional Materials and Big data, Guizhou Minzu University, Guiyang 550025, China
Zhangsen Chen
Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique (INRS), 1650 Boulevard Lionel-Boulet, Varennes, QC J3X 1P7, Canada
Hariprasad Ranganathan
Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique (INRS), 1650 Boulevard Lionel-Boulet, Varennes, QC J3X 1P7, Canada
Gaixia Zhang
Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique (INRS), 1650 Boulevard Lionel-Boulet, Varennes, QC J3X 1P7, Canada
Shuhui Sun
Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique (INRS), 1650 Boulevard Lionel-Boulet, Varennes, QC J3X 1P7, Canada
Developing cheap and earth-abundant electrocatalysts with high activity and stability for oxygen reduction reactions (ORRs) is highly desired for the commercial implementation of fuel cells and metal-air batteries. Tremendous efforts have been made on doped-graphene catalysts. However, the progress of phosphorus-doped graphene (P-graphene) for ORRs has rarely been summarized until now. This review focuses on the recent development of P-graphene-based materials, including the various synthesis methods, ORR performance, and ORR mechanism. The applications of single phosphorus atom-doped graphene, phosphorus, nitrogen-codoped graphene (P, N-graphene), as well as phosphorus, multi-atoms codoped graphene (P, X-graphene) as catalysts, supporting materials, and coating materials for ORR are discussed thoroughly. Additionally, the current issues and perspectives for the development of P-graphene materials are proposed.
