Synthesis of bismuth (III) oxide films based anodes for electrochemical degradation of reactive blue 19 and crystal violet

Abstract

The Bi2O3 films-based anodes were synthesized by electrodeposition of Bi on stainless steel substrate at constant current density and during different deposition times, fallowed by calcination, forming Bi2O3. The thickness of the films was determined by two methods: the observation under the microscope and by calculation from mass difference. Electrochemical proceses at the anodes were ivestigated by linear sweep voltammetry. At the anodes obtained within 2, 5, 10 and 15 minutes of deposition, two dyes, namely: Reactive Blue 19 and Crystal Violet, were decolorized by oxidation with •OH radical, generated from H2O2 decomposition at the anodes. Decoloration times of the anodes varied, and the shortest one was achieved with the anode obtained during 5 minutes of deposition, with the film thickness of 2.5±0.3 μm. The optimal H2O2 concentration for the dyes degradation was found to be 10 mmol dm-3. [Projekat Ministarstva nauke Republike Srbije, br. ТR 34008]

Keywords

• Bismuth (III) oxide
• anodes
• synthesis
• film thickness
• decoloration
• hydrogen peroxide