Air atmosphere available fast one-pot synthesis of VO2 nanoparticles with excellent thermochromic properties by a novel liquid-shielding method

Abstract

As a typical strongly correlated transition oxide, vanadium dioxide (VO2) based nanomaterials have drawn many research attentions these years due to the giant metal-to-insulator phase transition (MIPT) at around 68 °C. However, due to the complexities of the V–O system and interplays between various vanadium oxide phases, the synthesis of high-quality VO2 nanopowders is still fraught with many challenges, especially in air atmosphere. In this paper, we report a novel air atmosphere available liquid-shielding synthesis method for thermochromic VO2 nanoparticles, by using low-eutectic molten-salt (LiCl–KCl) as the liquid-state air-insulation medium at elevated temperature and high-pressure pressed VOSO4–KCl pillars immersed in these liquid salts as the precursor. Small amounts of glucose are added to introduce a slight reductive environment, and well dispersed VO2 nanoparticles with excellent thermochromic properties can be directly synthesized at an ultra-low temperature of 375 °C. This feasible and atmosphere-available mass-production method is rarely reported in the related fields, which may provide a novel protocol strategy for the synthesis of high performance thermochromic VO2 and other functional oxide powders.

Keywords

• Vanadium dioxide
• Nanoparticle
• Molten salt
• Liquid shielding
• Thermochromic properties