Bio-inspired lanthanum-ortho-quinone catalysis for aerobic alcohol oxidation: semi-quinone anionic radical as redox ligand

Abstract

A decade ago the first rare-earth-metal dependent enzyme was discovered, in which a non-redox lanthanide ion is central in the active site of a methanol dehydrogenase. Inspired by this discovery, here the authors show that an open-shell semi-quinone anionic radical species, complexed with lanthanum, could serve as a very efficient aerobic oxidation catalyst under ambient conditions.