(Acetylacetonato-κ2O,O′)bis{5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl-κ2N1,C1}iridium(III)

Abstract

In the title complex, [Ir(C16H9F2N2)2(C5H7O2)], the IrIII atom, lying on a twofold rotation axis, is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 5-fluoro-2-[3-(4-fluorophenyl)pyrazin-2-yl]phenyl ligands and one O,O′-bidentate acetylacetonate ligand. The dihedral angles between the benzene rings and the pyrazine ring are 14.66 (8) and 49.76 (12)°.