Acta Crystallographica Section E (Dec 2009)

Tetracarbonylbis(η5-cyclopentadienyl)bis[(dec-9-en-1-yl)diphenylphosphine]dimolybdenum(0)(Mo—Mo) tetrahydrofuran disolvate

  • David R Tyler,
  • Lev N. Zakharov,
  • Ginger Shultz

DOI
https://doi.org/10.1107/S1600536809046327
Journal volume & issue
Vol. 65, no. 12
pp. m1545 – m1545

Abstract

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The asymmetric unit of the title compound, [Mo2(η5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-molecules of the organometallic species and two solvent molecules. Both organometallic molecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η5-cyclopentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenylphosphine ligand.