Electron Beam Irradiation Isolates Cellulose Nanofiber from Korea “Tall Goldenrod” Invasive Alien Plant Pulp

Abstract

This work investigates the possibility of isolating cellulose nanofibers from pulps of tall goldenrod plant, which are invasive plants in Korea, by a convenient method, without strong acids or high-pressure homogenization, using electron beam irradiation (EBI). The obtained cellulose nanofibers were characterized by scanning electron microscopy (SEM), ultraviolet−visible (UV−vis) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and in terms of their mechanical properties. SEM showed that the initially isolated 10-μm-diameter cellulose fibers became more finely separated with increasing EBI dose, and that cellulose fibers treated with 300 kGy of EBI were separated into long cellulose nanofibers of around 160 nm in diameter. In addition, the paper samples prepared from more finely separated fibers generated by using higher doses of EBI had enhanced UV−vis transmittance. Via the XRD analysis, we observed that cellulose I in the EBI-treated cellulose fibers were gradually converted into a different type of cellulose similar to cellulose type II, as the EBI dose increased. Meanwhile, the TGA demonstrated that the finely separated cellulose fibers observed after administering the high EBI dose had lowered thermal stability due to the reduction of cellulose I but higher char yield. In addition, tensile strengths of paper samples increased with decreasing the diameters of their constituent fibers that result from the different EBI doses used in the preparation of the paper pulp.

Keywords

• Korean invasive alien plants
• electron beam irradiation
• cellulose nanofibers
• tall goldenrod