Molecules (Apr 2023)

A Facile Hydrothermal Synthesis and Resistive Switching Behavior of α-Fe<sub>2</sub>O<sub>3</sub> Nanowire Arrays

  • Zhiqiang Yu,
  • Jiamin Xu,
  • Baosheng Liu,
  • Zijun Sun,
  • Qingnan Huang,
  • Meilian Ou,
  • Qingcheng Wang,
  • Jinhao Jia,
  • Wenbo Kang,
  • Qingquan Xiao,
  • Tinghong Gao,
  • Quan Xie

DOI
https://doi.org/10.3390/molecules28093835
Journal volume & issue
Vol. 28, no. 9
p. 3835

Abstract

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A facile hydrothermal process has been developed to synthesize the α-Fe2O3 nanowire arrays with a preferential growth orientation along the [110] direction. The W/α-Fe2O3/FTO memory device with the nonvolatile resistive switching behavior has been achieved. The resistance ratio (RHRS/RLRS) of the W/α-Fe2O3/FTO memory device exceeds two orders of magnitude, which can be preserved for more than 103s without obvious decline. Furthermore, the carrier transport properties of the W/α-Fe2O3/FTO memory device are dominated by the Ohmic conduction mechanism in the low resistance state and trap-controlled space-charge-limited current conduction mechanism in the high resistance state, respectively. The partial formation and rupture of conducting nanofilaments modified by the intrinsic oxygen vacancies have been suggested to be responsible for the nonvolatile resistive switching behavior of the W/α-Fe2O3/FTO memory device. This work suggests that the as-prepared α-Fe2O3 nanowire-based W/α-Fe2O3/FTO memory device may be a potential candidate for applications in the next-generation nonvolatile memory devices.

Keywords